Chemainus River watershed: Water quality report for the 2024 dry season

A total of 12 water samples were collected from field locations within the Chemainus watershed on August 8, 2024 by the Raincoast Healthy Waters team alongside representatives of the Halalt and Penelakut First Nations. An additional 10 samples of tap water were obtained from homes and businesses located on the Halalt First Nation Reserve on the same day. 

Team

Raincoast: Peter Ross, Sam Scott, and Marie Noel

Halalt First Nation: Haley Moskal, Tim Thomas, Cosmo Roemer

Halalt First Nation logo.

A watershed based approach to sampling

Published on 2025 09 02.

Scott S, Moskal H, Noel M, and Ross PS. 2025. Chemainus River watershed: Water quality report for the 2024 dry season. Raincoast Conservation Foundation. https://doi.org/10.70766/2681.52

Acknowledgements

We acknowledge the financial support of the Halalt First Nation. We are grateful for the enthusiastic support of Haley Moskal, Tim Thomas, Ken Thomas and Cosmo Roemer. We acknowledge the expert analytical support of Pam MacKenzie and Richard Grace at SGS-AXYS. We thank Nicole Van Zutphen, Sherwin Arnott, and Brooke Gerle for report design. Photo credit Peter Ross, Isabella Fiddes and Samantha Scott.

Executive summary

Water is essential for life, and steps are needed to understand, protect and restore its health in fish habitat throughout British Columbia. The Raincoast Healthy Waters program was launched in 2023 to establish community-oriented water pollution monitoring in select BC watersheds. Two Healthy Waters sampling events take place every year in each watershed, the first in the dry season (summer), and the second being in the wet season (winter). This report highlights results from the first dry (summer) season sampling carried out with the support and participation of Halalt First Nation. 

Briefly, the Healthy Waters – Halalt team determined basic water properties (temperature, conductivity, pH, dissolved oxygen and turbidity) in situ at sampling sites on August 8, 2024. Water samples were collected from five water categories, including source water (3 sites), stream and river water (3 sites), road runoff (3 sites), and tap water (10 samples). The samples were pooled into composite by category and then analysed for coliform, nutrients (6), physical parameters, metals (37), pesticides (62), polycyclic aromatic hydrocarbons (PAHs; 76), pharmaceuticals and personal care products (PPCPs; 141), polychlorinated biphenyls (PCBs; 209), alkylphenol ethoxylates (APEs; 4), bisphenols (BPs; 6), per- and poly-fluoroalkyl substances (PFAS; 40), and sucralose. Analysis of 6PPD-Quinone is pending. We detected 91 contaminants out of 573 measured in the stream and river category – i.e. fish habitat – for the in the Chemainus River, excluding nutrients, fecal coliform and physical parameters. Overall, the Chemainus River watershed had relatively good water quality in the dry season, but additional sampling and analysis will provide additional insight into contamination impacts from forest fires, domestic wastewater, industrial chemicals and road runoff on the health of this valued watershed.

Chemainus River watershed

Map: The Chemainus River watershed covers an area of 356 km2, and runs eastwards from its source in the Vancouver Island Ranges, down towards the territories of the Halalt, Penelakut, and Lyackson First Nations, and the town of Chemainus, where it enters the Salish Sea.
The Chemainus River watershed covers an area of 356 km2, and runs eastwards from its source in the Vancouver Island Ranges, down towards the territories of the Halalt, Penelakut, and Lyackson First Nations, and the town of Chemainus, where it enters the Salish Sea. The Halalt originate from the village of xeláltxw, which means ‘marked houses’ or ‘painted houses’, a reference to the fact that the houseposts in this village were decorated. According to Cowichan oral history, the forefathers of both the Cowichan and Chemainus people (Siyóletse and St’éts’en respectively) originated from this village. Sampling sites were dispersed throughout the watershed in order to capture a wide spatial range to better understand potential impacts to water quality Map by Brooke Gerle/ Raincoast Conservation Foundation.

Key findings

  • This is the second assessment of water quality in the Chemainus River watershed; our understanding of water quality will build on the previous assessment, and will grow with additional sampling.
  • We collected and analysed water in the Chemainus River watersheds during the dry season (August 8, 2024).
  • Road runoff was the most contaminated water category in the dry season; it had the highest concentrations of PAHs, PPCPs, PFAS, and sucralose.
  • Marine water was the second most contaminated water category in the dry season; it had the highest concentration of metals, pesticides, and PCBs.
  • Source, tap, and stream and river water were less contaminated than the above water categories in the dry season.
  • The concentrations of E. coli, PCBs, and PPCPs were all notably higher in the dry season compared to the previous wet season sampling. 
  • The concentrations of nitrate, PFAS, and sucralose were notably higher in the previous wet season sampling, compared to this dry season. 
  • Overall, the Chemainus River watershed had relatively good water quality in the wet season:
    • There was one exceedance of Canadian Environmental Quality Guidelines; the temperature measured in the stream and river sites was above the BCMoE maximum daily value for temperature 19 ℃ for the protection of freshwater aquatic life with unknown fish distribution. .
    • There were no exceedances of Health Canada Drinking Water Quality Guidelines.

Background

Raincoast’s Healthy Waters Program delivers high-resolution, community-oriented water quality analysis to watersheds across southern British Columbia. The goal of Healthy Waters is to empower communities with the understanding of the status of water quality in their watersheds, to allow for local advocacy regarding both point and nonpoint source pollution. 

The Halalt People originate from the village of xeláltxw, which means ‘marked houses’ or ‘painted houses’, a reference to the fact that the houseposts in this village were decorated. According to information collected by Rozen (1985), this village was once located in the Cowichan Valley, at the spot where the Silver Bridge currently crosses the Cowichan River, at the south-eastern edge of the city of Duncan. According to Cowichan oral history, the forefathers of both the Cowichan and Chemainus people (Siyóletse and St’éts’en respectively) originated from this village.

The residents of this village later relocated to a village at the north end of Willy Island, the largest of the Shoal Islands located just off the mouth of the Chemainus River, perhaps in the early part of the 19th Century. When they moved, they took the village name with them. Rozen (1985) reports that, historically, there were at least five or six houses in the village on Willy’s Island. Although the entire island was designated an Indian Reserve (Halalt Island No. 1), the village was abandoned in the 1920s and the residents moved to the Westholme reserve on the lower Chemainus River (Halalt No. 2).

The Halalt have stewarded the land and waters of the Chemainus River watershed and surrounding areas since time immemorial.

Illustration of a watershed from mountain source to urban city and sea, with icons pointing out source water, freshwater, urban runoff, tap water, and marine environment.

A watershed based approach to sampling

We collect samples from five different categories of water in each of our partner watersheds: from source water, upstream of human impacts, down to the marine environment. 

Source water serves as an upstream reference sample, allowing us to determine which contaminants are being introduced as water traces its path down through the watershed. 

Stream and river samples allow us to investigate the quality of fish habitat directly, by collecting samples from streams, creeks, and rivers used by salmon and other fish species (either currently or historically). 

Road runoff serves as an impacted sample category of current concern, as many contaminants, including  PAHs, metals, surfactants and chemicals such as 6-PPD quinone can be washed off roadways and into fish habitat during rain events. 

We include tap water samples in our analysis as a way to bring our homes into the conversation – we borrow water from the environment in the form of municipal or well water, and generally return it to aquatic habitats in a more-degraded state in the form of storm and sewage effluent (treated or untreated).

Marine water samples provide insight into those contaminants that may degrade fish and whale habitat in the ocean, and enable an understanding of the contribution of land-based pollutants from the adjacent watershed to the marine environment.

Collectively, the lessons learned from our partnering watersheds will contribute to a greater understanding of threats to water quality across British Columbia, and ultimately what policy changes can be implemented to preserve the quality of water for the future of salmon, whales, and people.

References

Krista A. Barzen-Hanson, Simon C. Roberts, Sarah Choyke, Karl Oetjen, Alan McAlees, Nicole Riddell, Robert McCrindle, P. Lee Ferguson, Christopher P. Higgins, and Jennifer A. Field. 2017. Environmental Science & Technology 51: 2047-2057. DOI: https://doi.org/10.1021/acs.est.6b05843

Berthiaume, A., Galarneau, E., & Marson, G. (2021). Polycyclic aromatic compounds (PACs) in the Canadian environment: Sources and emissions. Environmental Pollution, 269, 116008.

Canadian Council of Ministers of the Environment, 1999. Canadian Sediment Quality Guidelines for the protection of aquatic life: Endrin. https://www.ccme.ca/en/res/endrin-canadian-sediment-quality-guidelines-for-the-protection-of-aquatic-life-en.pdf

CCME (Canadian Council of Ministers of the Environment). 1999. Canadian water quality guidelines for the protection of aquatic life—Dissolved oxygen (freshwater). Winnipeg. https://ccme.ca/en/res/dissolved-oxygen-freshwater-en-canadian-water-quality-guidelines-for-the-protection-of-aquatic-life.pdf 

Canadian Council of Ministers of the Environment. 2010. Canadian water quality guidelines for the protection of aquatic life: Ammonia. In: Canadian environmental quality guidelines, 1999, Canadian Council of Ministers of the Environment, Winnipeg. https://ccme.ca/en/res/ammonia-en-canadian-water-quality-guidelines-for-the-protection-of-aquatic-life.pdf 

CCME (Canadian Council of Ministers of the Environment). 2016. GUIDANCE MANUAL FOR DEVELOPING NUTRIENT GUIDELINES FOR RIVERS AND STREAMS. https://ccme.ca/en/res/guidancemanualfordevelopingnutrientguidelinesforriversandstreams.pdf 

Davis, J. 1975. Minimal Dissolved Oxygen Requirements of Aquatic Life with Emphasis on Canadian Species: a Review. Journal of the Fisheries Board of Canada. https://doi.org/10.1139/f75-268

Ding, Y., Hayward, S. J., Westgate, J. N., Brown, T. N., Lei, Y. D., & Wania, F. (2023). Legacy and current-use pesticides in Western Canadian mountain air: Influence of pesticide sales, source proximity, and altitude. Atmospheric Environment, 308, 119882.

Dongyoung Lee, Kyungho Choi. 2019. Comparison of regulatory frameworks of environmental risk assessments for human pharmaceuticals in EU, USA, and Canada. Science of The Total Environment 671, 1026-1035. https://doi.org/10.1016/j.scitotenv.2019.03.372.

Environment and Climate Change Canada (ECCC), 2023. Update on Canada’s National Implementation plan – Under the Stockholm Convention on Persistent Organic Pollutants. https://www.canada.ca/content/dam/eccc/documents/pdf/cepa/En14-517-2023-eng.pdf.  Accessed in May 2024. 

Environment and Climate Change Canada (ECCC) and Health Canada, 2023. Draft State of Per and polyfluoroalkyl substances (PFAS). https://www.canada.ca/en/environment-climate-change/services/evaluating-existing-substances/draft-state-per-polyfluoroalkyl-substances-report.html. Accessed in May 2024. 

Giardina A, Larson SE, Wisner B, Wheeler J, Chao M. Long-term and acute effects of zinc contamination of a stream on fish mortality and physiology. Environ Toxicol Chem. 2009 Feb;28(2):287-95. doi: 10.1897/07-461.1. PMID: 18937529.

Government of Canada, Environment and Climate Change Canada and Health Canada, 1994. Canadian Environmental Protection Act – Priority substances list assessment report – Polycyclic Aromatic Hydrocarbons. https://www.canada.ca/content/dam/hc-sc/migration/hc-sc/ewh-semt/alt_formats/hecs-sesc/pdf/pubs/contaminants/psl1-lsp1/hydrocarb_aromat_polycycl/hydrocarbons-hydrocarbures-eng.pdf. Accessed in May 2024.

Government of Canada, 2017. Toxic substances list – hexachlorobenzene (HCB). https://www.canada.ca/en/environment-climate-change/services/management-toxic-substances/list-canadian-environmental-protection-act/hexachlorobenzene.html. Accessed in May 2024. 

Health Canada, 2007. Pesticides and Health. https://www.canada.ca/content/dam/hc-sc/migration/hc-sc/ewh-semt/alt_formats/hecs-sesc/pdf/pubs/contaminants/pesticides-eng.pdf. Accessed in May 2024. 

Health Canada, 2010. Polychlorinated biphenyls. https://www.canada.ca/en/health-canada/services/chemical-substances/fact-sheets/chemicals-glance/polychlorinated-biphenyls.html. Accessed in May 2024. 

Health Canada, 2011. Discontinuation of endosulfan. https://publications.gc.ca/collections/collection_2011/sc-hc/H113-5-2011-1-eng.pdf. Accessed in May 2024.

Health Canada, 2016. Special review of simazine: proposed decision for consultation. https://publications.gc.ca/collections/collection_2016/sc-hc/H113-5-2016-9-eng.pdf. Accessed in May 2024.

Jadaa, W., Mohammed, H.K. 2023. Heavy Metals – Definition, Natural and Anthropogenic Sources of Releasing into Ecosystems, Toxicity, and Removal Methods – An Overview Study. 

J. Ecol. Eng. 2023; 24(6):249-27. DOI: https://doi.org/10.12911/22998993/162955

La, Van T. and Cooke, Steven J.(2011) ‘Advancing the Science and Practice of Fish Kill Investigations’, Reviews in Fisheries Science, 19: 1, 21 — 33, First published on: 15 December 2010 (iFirst) DOI: 10.1080/10641262.2010.531793

La Guardia, M.J., Hale, R.C., Harvey, E., and Mainor, T.M. 1999. Alkylphenol Ethoxylate Degradation Products in Land-Applied Sewage Sludge (Biosolids). Environ. Sci. Technol. 1999, 33, 9, 1366–1372. https://doi.org/10.1021/es980966z

Lalonde, B., Garron, C. Nonylphenol, Octylphenol, and Nonylphenol Ethoxylates Dissemination in the Canadian Freshwater Environment. Arch Environ Contam Toxicol 80, 319–330 (2021). https://doi.org/10.1007/s00244-020-00807-x

Li E, Saleem F, Edge TA, Schellhorn HE. Biological Indicators for Fecal Pollution Detection and Source Tracking: A Review. Processes. 2021; 9(11):2058. https://doi.org/10.3390/pr9112058

Lo, B. P., Marlatt, V. M., Liao, X., Reger, S., Gallilee, C., Ross, A. R. S., Brown, T. M. (2023). Acute Toxicity of 6PPD-Quinone to Early Life Stage Juvenile Chinook (Oncorhynchus tshawytscha) and Coho (Oncorhynchus kisutch) Salmon. Environmental Toxicology and Chemistry, 42(4), 741-947.

Longpré, D., Lorusso, L., Levicki, C., Carrier, R., and Cureton, P. 2020. PFOS, PFOA, LC-PFCAS, and certain other PFAS: A focus on Canadian guidelines and guidance for contaminated sites management. Environmental Technology & Innovation 18, 100752. https://doi.org/10.1016/j.eti.2020.100752.

Malhotra, N., Ger, T-R., Uapipatanakul, B., Huang, J-C., Chen K. H. C., Hsiao, C-D. 2020. Review of Copper and Copper Nanoparticle Toxicity in Fish. Nanomaterials. 10(6), 1126; https://doi.org/10.3390/nano10061126

Marvin, C. H., Berthiaume, A., Burniston, D. A., Chibwe, L., Dove, A., Evans, M., … & Tomy, G. T. (2021). Polycyclic aromatic compounds in the Canadian Environment: Aquatic and terrestrial environments. Environmental Pollution, 285, 117442.

Mehwish Faheem, Ramji Kumar Bhandari, Faheem, M., and Bhandari, R.K.. 2021. Detrimental Effects of Bisphenol Compounds on Physiology and Reproduction in Fish: A Literature Review. Environmental Toxicology and Pharmacology. Volume 81: 103497. https://doi.org/10.1016/j.etap.2020.103497.

Metcalfe, C., Miao, XS., Hua, W., Letcher, R., Servos, M. (2004). Pharmaceuticals in the Canadian Environment. In: Kümmerer, K. (eds) Pharmaceuticals in the Environment. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-09259-0_6

Möller, A., Ahrens, L., Surm, R., Westerveld, J., van der Wielen, F., Ebinghaus, R., and de Voogt, P. 2010. Distribution and sources of polyfluoroalkyl substances (PFAS) in the River Rhine watershed. Environmental Pollution 158: 3243-3250. https://doi.org/10.1016/j.envpol.2010.07.019.

Noël, M., Dangerfield, N., Hourston, R. A., Belzer, W., Shaw, P., Yunker, M. B., & Ross, P. S. (2009). Do trans-Pacific air masses deliver PBDEs to coastal British Columbia, Canada?. Environmental Pollution, 157(12), 3404-3412.

OppenheimerJ., Eaton, A., Badruzzaman, M., Haghani, A.W., and Jacangelo, J.G. 2011. Occurrence and suitability of sucralose as an indicator compound of wastewater loading to surface waters in urbanized regions. Water Research 45: 4019-4027: https://doi.org/10.1016/j.watres.2011.05.014.

Othman, N., Ismail, Z., Selamat, M. I., Sheikh Abdul Kadir, S. H., & Shibraumalisi, N. A. (2022). A review of polychlorinated biphenyls (PCBs) pollution in the air: where and how much are we exposed to?. International journal of environmental research and public health, 19(21), 13923.

Putt AE, MacIsaac EA, Herunter HE, Cooper AB, Selbie DT. Eutrophication forcings on a peri-urban lake ecosystem: Context for integrated watershed to airshed management. PLoS One. 2019 Jul 24;14(7):e0219241. doi: 10.1371/journal.pone.0219241. PMID: 31339893; PMCID: PMC6655610.

Ribeiro de Sousa, D.N., Mozeto, A.A., Carneiro, R.L., Fadini, P.S. 2014. Electrical conductivity and emerging contaminant as markers of surface freshwater contamination by wastewater,

Science of The Total Environment, Volume 484:19-26. https://doi.org/10.1016/j.scitotenv.2014.02.135. (https://www.sciencedirect.com/science/article/pii/S0048969714003295)

Rochester, J.R. 2013. Bisphenol A and human health: A review of the literature,

Reproductive Toxicology 42: 132-155. https://doi.org/10.1016/j.reprotox.2013.08.008.

Ross, P. S., Ellis, G. M., Ikonomou, M. G., Barrett-Lennard, L. G., & Addison, R. F. (2000). High PCB concentrations in free-ranging Pacific killer whales, Orcinus orca: effects of age, sex and dietary preference. Marine Pollution Bulletin, 40(6), 504-515.

Ross,P.S., Noël,M., Lambourn,D.M., Dangerfield,N., Calambokidis,J.C., and Jeffries,S.J. 2013. Declining concentrations of PCBs, PBDEs, PCDEs and PCNs in harbor seals from the Salish Sea. Progress in Oceanography 115: 160-170.

Rügner, H., Schwientek, M., Beckingham, B. et al. Turbidity as a proxy for total suspended solids (TSS) and particle facilitated pollutant transport in catchments. Environ Earth Sci 69, 373–380 (2013). https://doi.org/10.1007/s12665-013-2307-1

Rusydi, A.F. 2018 IOP Conf. Ser.: Earth Environ. Sci. 118 012019

Schulz, R. (2004). Field studies on exposure, effects, and risk mitigation of aquatic nonpoint‐source insecticide pollution: A review. Journal of environmental quality, 33(2), 419-448.

Schwartz, H., Marushka, L., Chan, H.M. et al. Pharmaceuticals in source waters of 95 First Nations in Canada. Can J Public Health 112 (Suppl 1), 133–153 (2021). https://doi.org/10.17269/s41997-021-00499-3

Shang, D., Macdonald, R.W. and Ikonomou, M.G. 1999. Persistence of Nonylphenol Ethoxylate Surfactants and Their Primary Degradation Products in Sediments from near a Municipal Outfall in the Strait of Georgia, British Columbia, Canada. Environ. Sci. Technol.: 33, 9, 1366–1372. https://doi.org/10.1021/es980966z

van Elsas, J.D., Semenov, A.V., Costa, R., Trevors, J.T. Survival of Escherichia coli in the environment: fundamental and public health aspects, The ISME Journal, Volume 5, Issue 2, February 2011, Pages 173–183, https://doi.org/10.1038/ismej.2010.80

van Stempvoort, D.L., Brown, S.J. Spoelstra, J., Garda, D., Robertson, W.D., and Smyth, S.A.. 2020. Variable persistence of artificial sweeteners during wastewater treatment: Implications for future use as tracers. Water Research 184: 116124. https://doi.org/10.1016/j.watres.2020.116124.